Experimental and computational study of Tm-doped TiO2: The effect of Li+ on Vis-response photocatalysis and luminescence

Applied Catalysis B: Environmental(2019)

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Abstract
•Enhanced Tm emission intensity by double TiO2 modification.•Formation of new Tm-f states below the CB of TiO2 during the synthesis process.•Bathochromic shift of absorption for Tm-TiO2 samples.•Enhanced photocatalytic activity under Vis irradiation for Tm-TiO2.•Higher electronic density in the TiO2 band gap region.
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Key words
TiO2,Thulium,Lithium,Visible light,PDOS
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