Catalytic Asymmetric Cyanation Reactions of Aldehydes and Ketones in Total Synthesis
Advanced Synthesis and Catalysis(2019)
摘要
Catalytic asymmetric cyanation reactions of aldehydes and ketones provide efficient routes for the synthesis of optically active cyanohydrins, which are versatile synthons for the preparation of natural products and chemical pharmaceuticals. This review aims to provide a summary of recent achievements concerning catalytic enantioselective cyanation reactions of aldehydes and ketones employed in the total syntheses of various natural products, drugs, and pharmaceutically active compounds.
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关键词
aldehydes and ketones,asymmetric cyanation reactions,chiral alcohols,optically active cyanohydrins,total syntheses
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