Effect of Formation Conditions on the Functional Composition of the Surface of High-Silica Porous Glass

Glass Physics and Chemistry(2019)

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摘要
The possibility of controlling the content and ratio of Brønsted acid to Lewis base centers on the surface of high-silica porous glass (PG) with various compositions based on two-phase alkali-borosilicate glass by varying the conditions of the preparation of PG during the acid work-up of the initial glass is shown. The results demonstrate the possibility to control the features of the surface of the PG, and in particular, the ratio of silanol to siloxane structures.
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关键词
porous glass,secondary silica,surface-active centers,Lewis and Brønsted centers,silicomolybdic heteropolyanion
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