Novel chiral diamidophosphites for asymmetric metal-catalyzed reactions

I. V. Chuchelkin,V. K. Gavrilov,V. S. Zimarev, I. D. Firsin,M. G. Maksimova,A. A. Shiryaev,S. V. Zheglov,K. N. Gavrilov

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS（2019）

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摘要

Chiral diamidophosphites with 1,3,2-diazaphospholidine cycles were prepared. A study of these chiral inducers showed them to provide up to 97% ee in the Pd-catalyzed allylic alkylation of (E)-1,3-diphenylallyl acetate with dimethyl malonate. [GRAPHICS] .

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关键词

Chiral diamidophosphites,1,3,2-diazaphospholidines,Pd-catalyzed asymmetric allylic alkylation

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