Reactivity of [Mo(CO)3(NCMe)3] towards pyrimidine-2-thiol (pymSH) and thiophenol (PhSH) in the presence of phosphine auxiliaries: Synthesis of mono- and dinuclear complexes bearing κ2 and µ,κ2-pymS coordination motifs

Roknuzzaman,S.M. Tareque Abedin,Mohd. Rezaul Haque,Shishir Ghosh,Derek A. Tocher,Michael G. Richmond,Shariff E. Kabir

Polyhedron（2019）

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摘要

A number of new mono- and di-molybdenum complexes have been isolated and characterized from the reactions of [Mo(CO)3(NCMe)3] with pmySH or PhSH in the presence of a phosphine.

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关键词

Mono- and di-molybdenum complexes,Thiol activation,Phosphine mediators,X-ray structures,DFT

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