The chemical interaction of support and active phase in sintering resistant La0.8Ca0.2FeO3 perovskite catalysts
Fuel(2019)
Abstract
•La0.8Ca0.2FeO3 perovskite (LCF)/n-MgAl2O4 spinel (MgAl), molar ratio n = 2.5 or 4, by deposition-precipitation.•The catalyst activity, sintering resistance and chemical stability of LCF/nMgAl are greatly improved over LCF.•MgAl promotes LCF via chemical modification of the active structure rather than physical segregation.
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Key words
Calcium doped LaFeO3 perovskite,MgAl2O4 spinel,Surface modification,Sintering resistance,Interaction mechanism
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