Rhodium(i)-catalyzed Pauson–Khand-type reaction using formic acid as a CO surrogate: an alternative approach for indirect CO₂ utilization

Xian-Dong Lang,Fei You,Xing He,Yi-Chen Yu,Liang-Nian He

Green Chemistry（2019）

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摘要

As a bridging molecule for the conversion of CO2 to CO, formic acid is successfully applied to rhodium-catalyzed carbo- and hetero-Pauson–Khand-type reactions, affording moderate to high yields of bicyclic cyclopentenones.

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formic acid,indirect co,pauson–khand-type

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Rhodium(i)-catalyzed Pauson–Khand-type reaction using formic acid as a CO surrogate: an alternative approach for indirect CO2 utilization

Rhodium(i)-catalyzed Pauson–Khand-type reaction using formic acid as a CO surrogate: an alternative approach for indirect CO₂ utilization