Silicon spheres for the future realization of the kilogram and the mole

New definitions of the units for amount of substance – the mole – and for mass – the kilogram – will presumably come into force on the World Metrology Day 2019. In the revised SI, the mole will be defined by a fixed value of the Avogadro constant and the kilogram by a fixed value of the Planck constant. The X-ray-crystal-density (XRCD) method has been used for the determination of these fundamental constants by counting the number of atoms in 28Si-enriched spheres. Thus, silicon spheres will – after the redefinition – be used to realize the definitions of the mole and the kilogram. This is possible by SI-traceable measurements of lattice parameter, isotopic composition, volume, and surface properties, yielding a relative standard uncertainty below 2⋅10−8. Whereas this high accuracy is only reached with isotopically enriched silicon, it is also planned to use natural silicon spheres on a slightly lower level of accuracy. The future definitions will allow also new realization methods using silicon, in particular for small mass values.