Separation of minor actinides from lanthanides using immobilized ligand systems: the role of the counterion
Heterocycles(2019)
摘要
A CyMe4-BTPhen functionalized silica gel that selectively extracts Am(III) over Eu(III) from 4 M HNO3 with a separation factor u003e 154 has been developed. Evidence is presented that the counterion surrounding the M(III) in the proposed 1:1 [BTPhen:M(III)] complex plays an important role in the complexation of Am(III) and Eu(III).
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关键词
immobilized ligand systems,lanthanides,minor actinides
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