Regioselective functionalization of gem-bis(trifluoromethylated) alkanols

Irena S. Akhrem,Dzhul’etta V. Avetisyan,Lyudmila V. Afanas’eva,Andrey A. Tyutyunov,Oleg I. Artyushin,Nikolai D. Kagramanov

Mendeleev Communications（2018）

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摘要

One-pot functionalization of sp3 C–H bond in 1,1,1-trifluoro-2-(trifluoromethyl)decan-2-ol with CO and nucleophiles under the action of superelectrophilic complex CBr4·2 AlBr3 affords products of neo-structure and remote functionalities.

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regioselective functionalization,gem-bis

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