Copper(I) Complexes with Anionic Acylthio- or Acylselenourea Ligands and N-Heterocyclic Carbenes or Phosphanes: Copper(I) Complexes with Anionic Acylthio- or Acylselenourea Ligands and N-Heterocyclic Carbenes or Phosphanes
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY(2018)
摘要
Copper(I) complexes containing acylthio- and selenoureato ligands can be accessed either by transmetallation from the corresponding silver compounds or by direct reaction of the acylthio/selenourea with a copper(I) precursor in the presence of base. Several examples of tricoordinate organocopper(I) complexes containing N-heterocyclic carbenes as well as tetrahedral bis(phosphane) copper(I) compounds are reported with their spectroscopic and structural characterization.
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关键词
Copper,Selenium,N-Heterocyclic Carbenes,X-ray crystallography
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