Synthesis and complexation of N,N-Bis(O-diethylhydroxyphosphorylmethyl)-N-butylamine

Rafael A. Cherkasov,Igor D. Shurygin,Airat R. Garifzyanov,Ildar I. Mirzayanov,Aynaz Z. Gaynullin,Kamil A. Ivshin,Olga N. Kataeva

PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS（2019）

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摘要

The acid-base and complexing properties of N,N-bis(O-diethylhydroxyphosphorylmethyl)-N-butylamine (H3L) with divalent metals were investigated in aqueous solution via the potentiometric titration method. The formation of 1:1 species has been established. The structure of complex N,N-bis(O-diethylhydroxyphosphorylmethyl)-N-butylamine with copper(II) was determined using an X-ray diffraction method. [GRAPHICS] .

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关键词

Acid-base properties,aminophosphonates,stability constants,complexation

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