Dimethyl Sulfoxide-Accelerated Reductive Deamination of Aromatic Amines with T-BuONO in Tetrahydrofuran
JOURNAL OF CHEMICAL RESEARCH(2018)
摘要
An efficient method for the conversion of aryl amines into arenes by a one-pot reductive deamination has been achieved. It was found the reductive deamination using t-BuONO in tetrahydrofuran could be accelerated by dimethyl sulfoxide and provided the deamination products with good yields under mild conditions. A plausible mechanism is discussed.
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关键词
diazotisation,dimethyl sulfoxide,reductive deamination,t-butyl nitrite,aromatic amines
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