Flexible high-temperature sheet-type electric heaters using m-aramid/functionalized MWCNTs hybrid nanofiber composites
Composites Part B: Engineering(2019)
摘要
Poly(m-phenylene isophthalamide) (m-aramid)/functionalized multi-walled carbon nanotube nanofibers (m-aramid/MWCNT-OH NFs) are prepared by electrospinning of the blended m-aramid/MWCNT-OH mixtures with MWCNT-OH contents of 0.1–1.0 wt%. Afterwards, the MWCNT-OH solutions (0.1–1.0 mg ml−1) dispersed in ethanol are further infiltrated into m-aramid/MWCNT-OH NF substrate via a facile solution casting method to obtain MWCNT-OH coated m-aramid/MWCNT-OH NF composites (MWCNT@m-aramid/MWCNT-OH NF composites). FE-SEM analysis demonstrates that the MWCNT-OH is well coated on the m-aramid/MWCNT-OH NF substrate, depending on the MWCNT-OH contents. The sheet resistance of as-fabricated MWCNT-OH@m-aramid/MWCNT-OH NF composites decreases largely from 2845 Ω □−1 to 158 Ω □−1 with the increase of MWCNT-OH concentrations from 0.1 to 1.0 mg ml−1, due to the percolation threshold of MWCNT-OH in the MWCNT-OH@m-aramid/MWCNT-OH NF composites. Besides, the obtained composites are flexible and reveal excellent electric heating performance. The maximum temperature of the MWCNT-OH(1.0 wt%)@m-aramid/MWCNT-OH NF composites is attained ca. 157 °C with high electric heating efficiency of 10.4 ± 1.8 mW/°C at small quantities (0.23 mg cm−2) of MWCNT-OH, suggesting that the MWCNT-OH(1.0 wt%)@m-aramid/MWCNT-OH NF composites can be applied as a promising high-temperature flexible sheet-type electric heaters.
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关键词
m-aramid,Carbon nanotube,Nanofiber composite,Flexible,Sheet-type electric heater
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