A bifunctional luminescent coordination polymer as recyclable sensor for detecting TNP and Fe3+ with high selectivity and sensitivity

Inorganica Chimica Acta(2019)

Cited 12|Views7
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Abstract
A new Cd(II)-MOFs were synthesized and structurally characterized. Complex 1 is promising bifunctional luminescent probe for highly selective and sensitive sensing TNP and Fe3+ ions through luminescence quenching effect, the Ksv are up to 1.03 × 105 and 1.84 × 105 M−1. The complex also exhibits good recyclability for detecting TNP. The quenching mechanisms were studied based on both experiments and calculation.
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Key words
Coordination polymer,Nitro aromatic explosives,Metal ions,Fluorescence sensing,Selectivity and sensitivity
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