A short synthesis of protected 3-deoxy-d-arabino-2-heptulosonates (DAH) from shikimic acid based on silyl group migration
Tetrahedron Letters(2018)
摘要
•A convenient approach to DHA derivatives from shikimic acid was developed.•The 1,4-O–O silyl group migration followed by cyclization gave the pyranose core.•The configuration of the final heptulosonates was confirmed by NOESY experiments.
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关键词
Oxoheptanals,Heptulosonates,Silyl group migration,Shikimic acid
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