Azaallyl-derived ring formation via redox coupling in first row transition metals

Elliott B. Hulley,Spencer P. Heins,Peter T. Wolczanski,Kyle M. Lancaster,Emil B. Lobkovsky

Polyhedron（2019）

引用 5|浏览44

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摘要

The reductive coupling of a chelated diimine ligand, Me2C(CHNCH2(2-py))2 (dmp(PM)2), by (TMEDA)TiCl2 afforded a Ti(IV) cyclopropanated species, Me2cPr(cis-2,3-NCH2(2-py)2TiCl2 (1), while di-azaallyl precursors were used to generate 7-membered ring chelates [{DBM(PI−)(PI2−)}CrIII]2 (4) and [{DBM(PI)(PI′)}Fe]2 (5).

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关键词

Titanium,Azaallyl,Cyclopropane,Bond formation,Magnesium

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