Improved conversion efficiency of 10% for solid-state dye-sensitized solar cells utilizing P-type semiconducting CuI and multi-dye consisting of novel porphyrin dimer and organic dyes

To realize highly efficient solid-state dye-sensitized solar cells (SDSCs), the absorption range of the dye should be extended to the near-IR range to increase short-circuit current density (J(sc)); a high J(sc) in turn requires a highly conductive p-type semiconductor. A newly developed dye (DIPDAB2) with a porphyrin dimer structure provided higher absorption coefficients than the conventional dye with a similar framework (DTBC) in the long wavelength range of 700-800 nm, leading to higher incident photon-to-current conversion efficiencies. The dip in the absorption spectrum of DIPDAB2 located at 500-700 nm between the Soret band and Q band was filled by combining with two kinds of organic dyes (D131 and D358). The multi-dye consisting of the three dyes realized a high J(sc) over 20 mA cm(-2). The use of copper iodide that has a higher conductivity than p-type organic semiconductors and copper complexes secured a high filling factor. Introduction of Li ions into the TiO2 photoelectrodes improved the open-circuit voltage (V-oc) along with a slight increase in J(sc). Light soaking also contributed to a higher V-oc. The conversion efficiency of the present SDSC was as high as 10%.