Unusually sharp FTIR ν(OH) bands and very weak OH⋯F hydrogen bonds in M2(H2O)1,2B12F12 hydrates (MNaCs)

Matthew R. Lacroix,Xiaoyan Gao,Yong Liu,Steven H. Strauss

Journal of Fluorine Chemistry（2019）

Cited 7|Views5

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Abstract

The FTIR ν(OH) bands of M2(H2O)n(B12F12) hydrates (MNa, K, Rb, Cs) are unusually narrow and are not as redshifted compared to the ν(OH) bands in spectra of other alkali metal salt hydrates.

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Key words

Superweak anion,ATR-FTIR,Alkali metal,Hydrates

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