Unusually sharp FTIR ν(OH) bands and very weak OH⋯F hydrogen bonds in M2(H2O)1,2B12F12 hydrates (MNaCs)
Journal of Fluorine Chemistry(2019)
Abstract
The FTIR ν(OH) bands of M2(H2O)n(B12F12) hydrates (MNa, K, Rb, Cs) are unusually narrow and are not as redshifted compared to the ν(OH) bands in spectra of other alkali metal salt hydrates.
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Key words
Superweak anion,ATR-FTIR,Alkali metal,Hydrates
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