Nickel-coordinated chiral enols and Michael addition intermediate stabilized by the Ni–C bond
Mendeleev Communications(2018)
摘要
A representative within a new class of chiral enol NiII complexes derived from a Schiff base of aminoacetone and (S)-2-N-(N-benzylprolinoylamino)benzophenone was prepared, and its performance in nucleophilic addition was estimated. The complex was inert towards aldehydes and activated C=C bonds but reacted with carboxylic anhydrides and di-tert-butyl acetylenedicarboxylate. An unusual Michael addition intermediate stabilized by the Ni–C bond was discovered in the latter reaction.
更多查看译文
关键词
chiral enols,michael addition intermediate,bond,nickel-coordinated
AI 理解论文
溯源树
样例
![](https://originalfileserver.aminer.cn/sys/aminer/pubs/mrt_preview.jpeg)
生成溯源树,研究论文发展脉络
Chat Paper
正在生成论文摘要