Palladium complexes bearing κ2-N,N and κ3-N,N,O pendant amine bis(phenolate) ligands

Inorganica Chimica Acta(2019)

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Abstract
•Pendant donors generate Pd complexes that are distinct from bridging donors.•Bulky amine bis(phenolate) ligands form coordinatively less saturated Pd complexes.•Computational studies suggest a bulky para substituent may direct complex behavior.
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Key words
Palladium,X-ray,NMR,Anagostic
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