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Enantioselective total syntheses of (−)-clavaminol A and deacetyl (+)-clavaminol H

Rachana Pandey,Anju Gehlawat,Ranjana Prakash,Satyendra Kumar Pandey

SYNTHETIC COMMUNICATIONS（2018）

Cited 3|Views9
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Abstract
An efficient enantioselective approach to the syntheses of (-)-clavaminol A and deacetyl (+)-clavaminol H is presented, starting from n-decanol. The synthesis features Sharpless asymmetric dihydroxylation (AD), regioselective epoxide formation/opening and -tosylation as key steps. [GRAPHICS] .
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Key words
2-amino-3-alkanols,clavaminols,cytotoxic,Sharpless AD,regioselective
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