Palladium-catalyzed C–H alkenylation of quinoxaline N-oxide enabled by a mono-N-protected amino acid

Márcia Silvana Freire Franco,Murilo Helder de Paula, Paulina Cecylia Glowacka,Fernando Fumagalli,Giuliano Cesar Clososki,Flavio da Silva Emery

Tetrahedron Letters（2018）

引用 9|浏览22

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摘要

•Novel styrylquinoxaline-N-oxides synthesized via palladium(II) C–H activation reaction.•Pivotal influence of mono-N-protected amino acid in this Fujiwara-Moritani reaction.•Mechanistic implications using mono-N-protected amino acid as the ligand.•Post modification to obtain the deoxygenated styrylquinoxaline derivatives.

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关键词

C–H activation,Quinoxaline,Palladium,Alkenylation

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