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Synthesis and thermal stability of rare earth compounds REF3, REF3·nH2O and (H3O)RE3F10·nH2O (RE = Tb − Lu, Y), obtained from sulphide precursors

I.A. Razumkova,O.V. Andreev, A.N. Boyko

Journal of Fluorine Chemistry（2018）

Cited 18|Views3
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Abstract
•The REF3&903·nH2O and (H3O)RE3F10&903·nH2O compounds were synthesized from RE2S3 and HF.•The REF3&903·nH2O compounds have an amorphous phase.•After heat treatment the REF3&903·nH2O and (H3O)RE3F10&903·nH2O compounds moved into a REF3 compound of crystal structure as β-YF3.
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Key words
Rare earth fluoride,Sulphides of rare earth elements,Zeolite type
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