The crystal structures of 1-(4-halo-2,3,5,6-tetrafluorophenyl)-3-benzylimidazolium bromides: The relative importance of anion–π, lone pair–π, π π stacking and halogen bonding interactions
Journal of Fluorine Chemistry(2018)
Abstract
•Orthogonal columns of π─π stacked polyfluorophenyl and phenyl rings in three directions.•Columns of alternating polyfluorophenyl rings and bromide anions.•Columns of alternating polyfluorophenyl rings and iodine atoms.•Comparison of the strengths of anion─π, lone pair─π, π─π stacking and halogen bonding interactions.
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Key words
Imidazolium salt,Anion–π interaction,Lone pair–π interaction,π–π stacking,Halogen bonding,Crystal structure
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