Merging Gold Catalysis and Brønsted Acid Catalysis for the Synthesis of Tetrahydrobenzo[b][1,8]naphthyridines
Advanced Synthesis and Catalysis(2018)
摘要
A gold(I)/Brønsted acid‐catalyzed cyclization of 2‐azidobenzaldehydes with 3‐aza‐1,6‐enynes has been developed for the synthesis of tetrahydrobenzo[b][1,8]naphthyridine derivatives. This protocol enabled the modular synthesis of tetracyclic heterocycles in one operation with water and nitrogen gas as the byproducts.
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关键词
Azides,gold catalysis,enynes,heterocycles,tandem reaction
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