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Synthesis and characterization of thienyl‐substituted methanofullerene dyads

ENVIRONMENTAL PROGRESS & SUSTAINABLE ENERGY(2018)

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Abstract
Two derivatives of methano[60]fullerene derivatives based on cyclopenta[c]thiophene were prepared as the precursors for polythiophene with fullerene side chains, and were fully characterized by NMR and MALDI TOF, the photo-electric and spectral properties were investigated through the analysis of UV and cyclic voltammetry. Meanwhile, the mono-adduct was applied as electron acceptor for bulk-heterojunction solar cell, which exhibited the power conversion efficiency of 0.5%. (c) 2017 American Institute of Chemical Engineers Environ Prog, 37: 1433-1437, 2018
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Key words
fullerene,photovoltaic,thiophene,solar cell
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