Catalytic carbonyl hydrosilylations via a titanocene borohydride–PMHS reagent system
CATALYSIS SCIENCE & TECHNOLOGY(2017)
Abstract
Reduction of a wide range of aldehydes and ketones with catalytic amounts of titanocene borohydride in concert with a stoichiometric poly(methylhydrosiloxane) (PMHS) reductant is reported. Preliminary mechanistic studies demonstrate that the reaction is mediated by a reactive titanocene(III) complex, whose oxidation state remains constant throughout the reaction.
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Key words
Catalysis
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