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2D-architecture via self-assembly of the novel sandwich-type polyoxometalate [Zn3.2Bi0.8(B-α-ZnW9O34)2]15−

Dashuai Liang, Qin Wang,Huan Li,Hongxia Zhao, Zhengdong Yu, Changlang Wu, Cong Sun,Siran Qian,Lubin Ni,Guowang Diao

Polyhedron（2017）

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Abstract
A novel 2D polyoxometalate framework is obtained from Zn2+-directed assembly of the new [Zn3.2Bi0.8(B-a-ZnW9O34)2]15− building block. Electrochemical behavior of the compound (1) is studied by cyclic voltammetry (CV) in sodium acetate buffer solution. Moreover, compound (1) also can act as a catalyst in the oxidation of cyclohexanol with hydrogen peroxide.
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Key words
Sandwiched polyoxometalate,2D-architecture,Crystal structure,Zinc,Bismuth
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