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Cu-catalyzed aerobic oxidative C–CN bond cleavage of benzyl cyanide for the synthesis of primary amides

Xiuling Chen,Yanhong Peng,Yan Li,Minghu Wu,Haibing Guo,Jian Wang,Shaofa Sun

RSC ADVANCES（2017）

Cited 8|Views8
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Abstract
An efficient method via copper-catalyzed aerobic oxidative amidation of benzyl cyanide for primary amides is successfully developed. Using readily available NH4Cl as a nitrogen source and Cu/O-2 as a catalytic oxidation system offers new opportunities for C-CN bond cleavage and primary amide bond formation.
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Key words
benzyl cyanide,c–cn bond cleavage,primary amides,synthesis,cu-catalyzed
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