Petrogenesis and tectonic implications of Late Devonian arc volcanic rocks in southern Beishan orogen, NW China: Geochemical and Nd–Sr–Hf isotopic constraints

Late Devonian (ca. 370Ma) volcanic rocks provide important information about the nature of magmatism during the tectonic transition between the Early and Late Paleozoic in the Beishan orogen, southern Central Asian Orogenic Belt. They are predominantly an andesitic–dacitic–rhyolitic assemblage, characterized by alkali contents ranging from slightly calcic to slightly alkaline. The rhyolitic rocks are generally ferroan, whereas the andesitic rocks are magnesian. These volcanic rocks exhibit similar trace element characteristics to those of continental arcs. Strongly negative εNd(t) values (−2.8 to −3.6) and high Sr isotopic compositions (initial 87Sr/86Sr=0.7036–0.7108) suggest that they are mainly derived from an ancient crust. However, the positive zircon εHf(t) values (+1.4 to +16.4) support the role of juvenile components in their genesis, indicating the significant input of new mantle-derived magmas. These characteristics imply a hybrid derivation, from an ancient crustal source with the addition of juvenile materials during magma genesis, or perhaps heterogeneous contamination or hybridization during magma emplacement. Combined with the regional geology, our results indicate that the Late Devonian magmatism resulted from a southward retreat of the subduction zone, which records significant continental crustal growth in a transitional arc or an accretionary arc setting. The distinct geochemical compositions, especially the Nd–Hf isotope decoupling of the Dundunshan volcanic rocks, imply a significant change in the geodynamic setting in the Late Paleozoic.