Semifluorinated alkanes and alkanes : a phase study of the perfluorohexyloctane - tetradecane system

The Journal of Chemical Thermodynamics(2017)

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Abstract
•The phase diagram of perfluorohexyloctane – tetradecane system was determined.•The activity coefficients were calculated from the data on the phase behavior.•Enthalpies of solution at infinite dilution were measured.•Below −5.9°C perfluorohexyloctane was found to form a lamellar ripple phase.
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C14,DSC,F6H8,ITC,SAXS,SFAs,SWAXD
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