Structural characterization of some adducts of the form [M 2 (μ-dppm) 2 (MeCN) x ]X 2 [M=Cu, Ag; X=ClO 4 , BF 4 , PF 6 ; dppm=(Ph 2 P) 2 CH 2 ; x=0–4]

Inorganica Chimica Acta(2016)

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Abstract
Structures of several Cu and Ag complexes [M2(μ-dppm)2(NCMe)x]X2 (M=Cu, Ag; x=3, 4; X=BF4, PF6) are described, some of which show significant bridging interactions between M and the anions.
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Key words
Copper(I),Silver(I),Crystal structure,dppm ligand,Binuclear complex
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