Polymérisation anionique du styrène à hautes températures et à fortes concentrations en monomère dans l'éthylbenzène
European Polymer Journal(1998)
Abstract
The thermal decomposition of ethylbenzene solutions of n-butyllithium and polystyryllithium was observed between 50 and 100°C by gas chromatography and UV spectoscopy, respectively. The initiator shows poor stability but the polymerisation can lead to controlled molecular weights of living polymers by using a high concentration of monomer (about 50% weight).
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