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Mössbauer investigation of novel pentadentate schiff base complexes

L. Heyer,B. Dreyer,A. Preiss, M. Menze,S. Klimke, M. Jahns,R. Sindelar,G. Klingelhöfer,B. F. O. Costa,F. Renz

Hyperfine Interactions（2016）

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Abstract
We synthesised a series of seven mononuclear and two trinuclear Schiff base coordination compounds. All nine complexes have been analysed by Mössbauer and IR spectroscopy. The Mössbauer spectra reveal a doublet, which are related to the high spin state (S = 5/2) of the iron(III) centres.
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Key words
Schiff base, High spin, Iron complexes, Pseudohalide, Mössbauer
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