A highly practical approach to chiral homoallylic–homopropargylic amines via aza-Barbier reaction

Bin-Hua Yuan,Zhi-Cheng Zhang,Wen-Jie Liu,Xing-Wen Sun

Tetrahedron Letters（2016）

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摘要

•The first access to chiral homoallylic–homopropargylic amine bearing two contiguous stereocenters.•A novel allylic bromide was illustrated in aza-Barbier reaction.•Enantioenriched 3,4-dihydro-2H-pyrroles was prepared in high efficiency via 5-indo-dig pathway.

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关键词

aza-Barbier reaction,Homoallylic–homopropargylic amine,N-tert-Butanesulfinyl imine

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