Synthetic studies toward tetrapetalone A: attempted palladium π-allyl cascades toward a fused tricyclic intermediate
Tetrahedron(2016)
摘要
Efforts to install the core azepine ring in tetrapetalone A via a palladium π-allyl cascade reaction failed due to competing pathways that included an unexpected and interesting TMM-like cycloaddition reaction that delivers a complex tricyclic ring system.
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关键词
Palladium,Cascade,Pi-Allyl,Heterocycle,Tetrapetalone
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