Reaction of 3,4,6-Triisopropyl- о -benzoquinone with 3,4,6-Triisopropylcatechol
Russian Journal of General Chemistry(2018)
摘要
Formation of protonated 3,4,6-triisopropylsemiquinone radicals in solution of a mixture of 3,4,6- triisopropyl- о -benzoquinone and 3,4,6-triisopropylcatechol was shown using ESR spectroscopy. Heating the mixture to 110°С leads to the formation of the condensation products, additional amount of 3,4,6-triisopropylcatechol, and evolution of propylene. Mathematical simulation of the kinetics of the reaction was performed.
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关键词
о-quinone, catechol, ESR spectroscopy, condensation
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