Synthesis and structural features of new pentacoordinated monofluorosilanes containing C,O-chelate ligands based on 2-amino acid N -methylamides

A. A. Nikolin,A. A. Korlyukov,E. P. Kramarova,D. E. Arkhipov,A. G. Shipov,Yu. I. Baukov,Vad. V. Negrebetsky

Russian Chemical Bulletin（2018）

Cited 3|Views50

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Abstract

Pentacoordinated monofluorosilanes R 1 SO 2 NHCHR 2 C(O)N(Me)CH 2 SiMe 2 F containing moieties of N′ -methyl- N -(organosulfonyl)-2-amino acid amides of glycine, alanine, and leucine as C,O-chelating ligands were synthesized via the reaction of corresponding disiloxanes with BF 3 •Et 2 O. The structures of obtained compounds were investigated by single-crystal X-ray diffraction analysis.

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Key words

silicon-containing amino acids,pentacoordinated silicon compounds,syn thesis,X-ray diffraction analysis

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