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Co(II)-Catalyzed Regioselective Pyridine C–H Coupling with Diazoacetates

Haisheng Xie,Youxiang Shao,Jiao Gui,Jianyong Lan,Zhipeng Liu,Zhuofeng Ke,Yuanfu Deng,Huanfeng Jiang,Wei Zeng

Organic Letters（2019）

Cited 21|Views25
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Abstract
A Co­(II)-catalyzed pyridyl C–H bond carbenoid insertion with α-diazoacetates has been realized. This transformation features a highly regioselective C–C bond formation at the C3-position of pyridines, providing an efficient access to diverse α-aryl-α-pyridylacetates.
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diazoacetates
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