Coexistence Of Magnetic Order And Persistent Spin Dynamics In A Quantum Kagome Antiferromagnet With No Intersite Mixing

One of the key questions concerning frustrated lattices that has lately emerged is the role of disorder in inducing spin-liquid-like properties. In this context, the quantum kagome antiferromagnet YCu3(OH)(6)Cl-3, which has been recently reported as the first geometrically perfect realization of the kagome lattice with negligible magnetic/nonmagnetic intersite mixing and a possible quantum-spin-liquid ground state, is of particular interest. However, contrary to previous conjectures, here we show clear evidence of bulk magnetic ordering in this compound below T-N = 15 K by combining bulk magnetization and heat capacity measurements, and local-probe muon spin relaxation measurements. The magnetic ordering in this material is rather unconventional in several respects. First, a crossover regime where the ordered state coexists with the paramagnetic state extends down to T-N/3 and, second, the fluctuation crossover is shifted far below T-N. Moreover, persistent spin dynamics that is observed at temperatures as low as T/T-N = 1/300 could be a sign of emergent excitations of correlated spin loops or, alternatively, a sign of fragmentation of each magnetic moment into an ordered and a fluctuating part.