Electrodeposited AgCu Foam Catalysts for Enhanced Reduction of CO 2 to CO.

Selective electrochemical reduction of CO is an emerging field which needs more active and stable catalysts for its practicability. In this work we have studied the influence of Ag metal incorporation into Cu dendritic structures on the product distribution and selectivity of CO electroreduction. Bimetallic AgCu foams prepared by hydrogen bubble templated electrodeposition shift the potentials of CO production to more positive values compared to bulk silver. The presence of Ag during the electrodeposition significantly changed the size and the shape of the dendrites in the pore walls of AgCu foams compared to Cu foam. The CO adsorption characteristics are studied by operando Raman spectroscopy. In the presence of Ag, the maximum CO adsorption is observed at a more positive potential. As a result, an improved selectivity for CO is obtained for AgCu foam catalysts at lower overpotentials compared to Cu foam catalyst, evidencing a synergistic effect between the bimetallic components. We were successful in increasing the CO mass activity with respect to the total Ag amount. AgCu foams are found to retain the CO selectivity during long term operation, and with their easily scalable electrodeposition synthesis they possess high potential for industrial application.