Catalytic Conjunctive Coupling of Carboxylic Acid Derivatives with 9-BBN-Derived Ate Complexes.
Angewandte Chemie (International ed. in English)(2019)
摘要
β-Boryl carbonyl compounds are produced by a Ni-catalyzed cross-coupling of vinylboron "ate" complexes and acid chloride or acid anhydride electrophiles. The reactions are efficient, being complete in as little as two minutes, and can be applied to a broad range of substrates.
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