Crystal growth of off-stoichiometric Co2Cr1-xAl1+x Heusler compounds: Avoiding the solid state miscibility gap
Journal of Crystal Growth（2018）
Abstract
•Floating zone technique gives access to low temperature phase dynamics.•Spinodal decomposition decreases as Cr is systematically substituted with Al.•Off-stoichiometry allows to move out of the solid state miscibility gap.•Extent and nature of miscibility gap highlighted in Co2CrAl-CoAl pseudo-binary phase diagram.
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Key words
B2. Heusler compounds,A2. Floating zone technique,A1. Phase diagram,A1. Off-stoichiometry,A1. Spinodal decomposition
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