Fragmentation of imidazole, pyrimidine and purine induced by core ionization : Significance of small-scale chemical environment

E. Itälä,Sari Granroth,D. T. Ha,K. Kooser,Helena Levola,Elisabeth Rachlew,Katrin Tanzer,Edwin Kukk

Journal of Photochemistry and Photobiology A: Chemistry（2018）

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摘要

•Fragmentation patterns following core ionization are presented.•The fragmentation is characterized by the production of CH1,2N+ ions.•Effect of small-scale chemical environment on molecular fragmentation is considered.•The effect varies between samples and is very hard to predict.

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关键词

Biomolecules,Ionization,Fragmentation,Chemical environment

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