Managing nucleophilic addition reactions to tune the physical properties of 2-substituted pentamethylBODIPY derivatives
RSC ADVANCES(2017)
Abstract
The synthesis and characterization of a family of 2-substituted BODIPY dyes are reported herein. The dyes have been prepared using nucleophilic addition reactions (Wittig reactions, imine, Knoevenagel & aldol condensations) which are typically more challenging for BODIPY ring systems. Structure-property relationships have also been delineated by evaluating the physicochemical properties including; absorption & emission spectroscopy, electrochemical studies (CV, DPV) and theoretical calculations (TD-DFT).
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Key words
nucleophilic addition reactions,derivatives
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