Fischer-Tropsch synthesis over MOF-supported cobalt catalysts (Co@MIL-53(Al)).

V I Isaeva,O L Eliseev,R V Kazantsev,V V Chernyshev, P E Davydov,B R Saifutdinov,A L Lapidus,L M Kustov

DALTON TRANSACTIONS（2016）

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Abstract

Novel nanohybrid materials were prepared by immobilizing Co nanoparticles on a microporous framework MIL-53(Al) as a porous host matrix. The synthesized cobalt-containing materials were characterized by XRD, STEM, and oxygen titration. The catalytic performance of Co@MIL-53(Al) nanohybrids was examined in Fischer-Tropsch synthesis (FTS) for the first time. A higher selectivity to C5+ hydrocarbons and lower selectivity to methane for Co@MIL-53(Al) as compared to conventional Co/Al2O3 were observed.

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Key words

cobalt catalysts,fischer–tropsch synthesis,mof-supported

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