A Hexakis Terpyridine-Fullerene Ligand in Six-Fold Ruthenium, Iridium, and Iron Complexes: Synthesis and Electrochemical Properties.
CHEMISTRY-A EUROPEAN JOURNAL(2016)
摘要
An unprecedented straightforward route to sixfold terpyridine ligands around C60, the latter being regioselectively functionalized in pseudo-octahedral positions using a six-fold Bingel reaction, is reported. Ruthenium, iridium, and iron complexes have been synthesized, and unambiguously characterized by NMR, MS, and cyclic voltammetry.
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关键词
crown ether,fullerene,metal complexes,nanostructures,terpyridine
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