The impact of modifying the ligands on hydrogen production electro-catalyzed by meso-tetra-p-X-phenylporphin cobalt complexes, CoT(X)PP

Yin Liu,Ling-Zhi Fu,Le-Min Yang,Xiao-Ping Liu,Shu-Zhong Zhan,Chun-Lin Ni

Journal of Molecular Catalysis A: Chemical（2016）

引用 15|浏览4

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摘要

•Reaction of meso-tetra-p-X-phenylporphin, H2T(X)PP with cobalt compound afford CoT(Cl)PP (1) and CoT(OMe)PP (2).•Meso-tetra-p-chloro-phenylporphin, CoT(Cl)PP (1) constitutes the better active catalyst than CoT(OMe)PP (2).•The cobalt complexes with more positive CoII/I redox potentials show lower activity for hydrogen generation.

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关键词

Porphin-cobalt complexes,Molecular electrocatalysts,Water reduction,Hydrogen evolution

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