Anisotropic strain induced soliton movement changes stacking order and bandstructure of graphene multilayers.

Deterministic control over the electronic properties of solid-state matter is considered as highly rewarding to understand interaction interaction-driven electronic effects. For example, in graphene stacks the electronic properties are greatly affected by the lateral layer arrangement as the most stable configurations, Bernal and rhombohedral stacking, exhibit very different electronic properties. Nevertheless, they can coexist within one flake, separated by a strain soliton that can host topologically protected states. Clearly, accessing the transport properties of both stackings and the soliton is of high interest. However, the stacking orders can transform into one another and therefore, the seemingly trivial question whether reliable electrical contact can be made to either stacking order can a priori not be answered easily. Here, we show that manufacturing metal contacts to multilayer graphene can move solitons by several micrometers, unidirectionally enlarging Bernal domains due to arising mechanical strain. Using DFT-modeling we corroborate that anisotropic deformations of the multilayer graphene lattice increase the Bernal-stacking stability over the otherwise energetically favored rhombohedral stacking. Finally, we have devised systematics to avoid soliton movement, and how to achieve stable contacts to both stacking configurations.